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Creators/Authors contains: "Clouthier, Samantha Marie"

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  1. ; ; (, Polymer Chemistry)
    Here we report the modelling of thermally initiated RAFT step-growth polymerization kinetics of maleimide and acrylate monomers with bifunctional RAFT agents bearing tertiary carboxyalkyl-stabilized fragmentable R groups. 
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    Free, publicly-accessible full text available January 14, 2026
  2. ; ; ; (, Polymer Chemistry)
    Here, we report the modelling of photo-mediated RAFT step-growth polymerization kinetics of maleimide and acrylate monomers with bifunctional RAFT agents bearing tertiary carboxyalkyl stabilized fragementable R groups. 
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    Free, publicly-accessible full text available January 1, 2026
  3. ; ; ; (, Macromolecular Rapid Communications)
    Abstract Photomediated reversible addition fragmentation chain transfer (RAFT) step‐growth polymerization is performed using a trithiocarbonate‐based chain transfer agent (CTA) and acrylate‐based monomers both with and without a photocatalyst. The versatility of photo‐mediated RAFT step‐growth is demonstrated by one‐pot synthesis of a graft copolymer via sequential monomer addition. Furthermore, oxygen‐tolerant photo‐mediated RAFT step‐growth is demonstrated, facilitated by the appropriate selection of photocatalyst and solvent pair (zinc tetraphenyl porphyrin [ZnTPP] and dimethyl sulfoxide [DMSO]), enabling ultralow volume polymerization under open‐air conditions. 
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    Free, publicly-accessible full text available January 1, 2026
  4. ; ; ; (, Polymer Chemistry)
    Here we report one-pot stimuli-responsive tandem degradation of a graft copolymer with alternating backbone functionalities. 
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  5. ; ; ; ; ; ; ; (, Chemical Science)
    RAFT step-growth polymerizationviathe Z-group approach was developed, offering a facile method to prepare deconstructable (multiblock) polymers by combining RAFT chain-growth polymerization and RAFT interchange. 
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  6. ; ; ; ; (, ACS Macro Letters)
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  7. ; ; ; (, Chemical Communications)
    RAFT step-growth polymerization is an emerging method that synergistically combines the benefits of RAFT polymerization (functional group and user-friendly nature) and step-growth polymerization (versatility of the polymer backbone). 
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  8. ; ; (, Polymer Chemistry)
    Photomediated RAFT step-growth polymerization was performed with and without the presence of a photocatalyst using a trithiocarbonate-based CTA and a maleimide monomer. Under catalyst-free conditions, the polymerization proceeded with an appreciable rate under irradiation with blue and green light, which was extended to red light in the presence of ZnTPP. 
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